有机磷

Abstract(#br)A novel hyphenated technique, namely the combination of stir bar sorptive extraction (SBSE) with isotope dilution direct analysis in real time (DART) Orbitrap™ mass spectrometry (OT-MS) is presented for the extraction of phosphoric acid alkyl esters (tri- (TnBP), di- (HDBP), and mono-butyl phosphate (H2MBP)) from aqueous samples. First, SBSE of phosphate esters was performed using a Twister™ coated with 24\u003cce:hsp sp=\"0.25\"/\u003eμL of polydimethylsiloxane (PDMS) as the extracting phase.

Organophosphorus pesticides (OPPs), widely known as persistent organic pollutants, are the most popular contaminants in agriculture products in developing countries. The determination of OPPs in complex matrices, such as food, environmental and biological samples, usually requires extensive sample pretreatment. This review focuses on the sorptive extraction techniques applied as sample pretreatment for OPPs in complex matrices, including solid-phase extraction (SPE) and solid-phase microextraction (SPME).