固相微萃取

Abstract(#br)Dynamic headspace solid-phase microextraction (HS-SPME) followed by thermal desorption gas chromatography-quadrupole mass spectrometry analysis (GC- q MS), was used to investigate the aroma profile of different species of passion fruit samples. The performance of five commercially available SPME fibres: 65 μm polydimethylsiloxane/divinylbenzene, PDMS/DVB; 100 μm polydimethylsiloxane, PDMS; 85 μm polyacrylate, PA; 50/30 μm divinylbenzene/carboxen on polydimethylsiloxane, DVB/CAR/PDMS (StableFlex); and 75 μm carboxen/polydimethylsiloxane, CAR/PDMS; was evaluated and compared.

Abstract(#br)A new polyethylene glycol fiber was developed for solid-phase microextraction (SPME) of styrene by electrodepositing porous Zn film on Ag wire substrate followed by coating with polyethylene glycol sol–gel (Ag/Zn/PEG sol–gel fiber). The scanning electron micrographs of fibers surface revealed a highly porous structure. The extraction property of the developed fiber-to-styrene residue from polystyrene packaged food was investigated by headspace solid-phase microextraction (HS-SPME) and analyzed with a gas chromatograph coupled with flame ionization detection (GC-FID).

Abstract(#br)Polybrominated diphenyl ethers (PBDEs) are brominated flame retardants (BFRs). The ubiquity and persistence of PBDEs in sediment have raised concerns over their environmental fate and ecological risks. Due to strong affinity for sediment organic matter, environmental fate and bioavailability of PBDEs closely depend on their phase distribution. In this study, disposable polydimethylsiloxane (PDMS) fiber was used to derive the freely dissolved concentration ( C free ) of PBDEs in sediment porewater as a measurement of bioavailability.

Abstract(#br)A modified procedure for the production of porous polydimethylsiloxane (PDMS) beads is presented which results in non-polar polymer beads with microscale concavity and therefore an increased surface-area-to-volume ratio. The key modification is the simple addition of a platinum catalyst to the emulsion prior to thermal curing. Elemental analysis of beads indicates the presence of platinum at the center of many of the indentations, which provides insight into the synthetic mechanisms.

Abstract(#br)In this study, a novel and efficient method based on headspace solid-phase microextraction (HS-SPME), followed by gas chromatography–mass spectrometry (GC–MS), was developed for the analysis of propolis volatile compounds. The HS-SPME procedure, whose experimental parameters were properly optimized, was carried out using a 100\u003cce:hsp sp=\"0.25\"/\u003eμm polydimethylsiloxane (PDMS) fiber.

Abstract(#br)Megastigmatrienone is a key flavor compound in tobacco.

Abstract(#br)In this work cobalt oxide nanoparticles were introduced for preparation of a novel solid phase microextraction (SPME) fiber coating. Chemical bath deposition (CBD) technique was used in order for synthesis and immobilization of the Co 3 O 4 nanomaterials on a Pt wire for fabrication of SPME fiber. The prepared cobalt oxide coating was characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD) analysis. The fiber was evaluated for the extraction of benzene, toluene, ethylbenzene and xylene (BTEX) in combination with GC–MS.

Abstract(#br)A superior solid-phase microextraction (SPME) fiber-coating material, IRMOF-3@ILs/PDMS, was prepared by the in situ growth of IRMOF-3 onto stainless-steel wires and protection with ionic liquids (ILs) and polydimethylsiloxane (PDMS). The ILs can efficiently prevent the substantial cracking of IRMOF-3 caused by moisture, and a thin PDMS film can protect the IRMOF-3@ILs material to achieve a much better extraction efficiency as well as excellent resistance to high temperature and high humidity.

Abstract(#br)Phthalates are a group of synthetic compounds mainly used as plasticizers, which have been classified as endocrine-disrupting chemicals and potential human-cancer causing agents. They can be found in high amounts in foods, deriving mainly from plastic packaging. The analytical determination of these compounds is very challenging since they are ubiquitous. Therefore, minimization of sample manipulation is highly desirable.(#br)The present work exploited the application of a solid-phase microextraction method for the analysis of phthalates in vegetable oil.

Abstract(#br)The monodisperse microporous carbon nanospheres (MMCNSs) were applied in solid phase microextraction for the first time. The MMCNSs-fiber was prepared by sol–gel technique and good repeatability and reproducibility were obtained, due to the excellent monodispersity of the MMCNSs.