Preparation and characterization of inorganic–organic trilayer core–shell polysilsesquioxane/polyacrylate/polydimethylsiloxane hybrid latex particles
Abstract(#br)The inorganic–organic trilayer core–shell polysilsesquioxane/polyacrylate/polydimethylsiloxane hybrid latex particles have been successfully prepared via seeded emulsion polymerization of acrylate monomers and octamethylcyclotetrasiloxane (D 4 ) gradually, using functional polymethacryloxypropylsilsesquioxane (PSQ) latex particles with reactive methacryloxypropyl groups synthesized by the hydrolysis and polycondensation of (3-methacryloxypropyl)trimethoxysilane in the presence of mixed emulsifiers as seeds.