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Microporous frameworks based on adamantane building blocks: Synthesis, porosity, selective adsorption and functional application

ty10086 提交于 周四, 08/26/2021 - 13:01
AbstractTwo microporous organic frameworks based on adamantane (hereafter denoted as MF-Ads) were fabricated through Sonogashira-Hagihara coupling polycondensation of aryl halides and alkynes. Results show that both types of MF-Ad networks had similar porous properties and exhibited excellent CO2 uptake capacity (72.5 cm3 g−1) and CO2/N2 selectivity (59.1) at 273 K and 1.0 bar. Taking advantage of the superhydrophobic wettability of the resulting MF-Ad networks, wire mesh scaffolds were used to fabricate superhydrophobic films with polydimethylsiloxane (PDMS) acting as a binder.