基于聚合物/银纳米线纳米复合材料的医用应变传感器的制备:硅氧烷基与聚氨酯基纳米复合材料

ty10086 提交于 周三, 08/25/2021 - 16:28
文章英文标题
Fabrication of a strain sensor based on polymer/silver nanowires nanocomposite for medical applications: Siloxane based versus urethane based nanocomposites
正文
本研究制备了基于聚二甲基硅氧烷( PDMS )和热塑性聚氨酯( TPU )两种聚合物基体以及银纳米线导电纳米材料( AgNWs )的应变传感器。传感器采用类似夹层的形貌布置,其中AgNWs层( s )嵌入PDMS或TPU的聚合层。研究了聚合物基体类型和导电层数量对传感器性能的影响。分析了传感器的形貌和机电特性,包括电阻( R )、电阻变化对应变的敏感性、电阻随应变变化的线性度以及传感器响应循环载荷的重复性。实验结果证实,随着导电层由1层增加到3层,在各自的PDMS和TPU基传感器中电阻分别下降了53 %和61 %。而且,PDMS和TPU基传感器的灵敏度分别下降了78 %和77 %。计算最大ΔR / R0值的相对SD ( RSD ),证实了传感器能够代表对顺序加载/卸载循环的可重复响应。重复性随导电层由1层增加到2层而降低,随导电层进一步增加而增强。在聚合物类型方面,TPU基传感器的电阻和重复性高于PDMS传感器,而灵敏度低于PDMS传感器。
文章内容(英文)
In the current study, strain sensors based on two polymer matrixes of polydimethylsiloxane (PDMS) and thermoplastic polyurethane (TPU) and conductive nanomaterials of the silver nanowires (AgNWs) were fabricated. The sensors were arranged with a sandwich like morphology in which AgNWs layer(s) were embedded with polymeric layers of PDMS or TPU. The effect of the polymer matrix type and the number of the conductive layers on sensor properties has been evaluated. Morphology and electromechanical properties of the sensors including electrical resistance (R), sensitivity of the resistance change to strain, linearity of the resistance change with strain and repeatability of the sensor response to cyclic loading were analyzed. The experimental results corroborated that with increasing conductive layers from one to three, the resistance decreased by 53% and 61% in respective PDMS and TPU based sensors. Moreover, the sensitivity decreased by 78% and 77% in PDMS and TPU based sensors, respectively. The calculation of the relative SD (RSD) of the maximum ΔR/R0 values substantiated that sensors were able to represent a repeatable response to the sequential loading/unloading cycles. The repeatability was decreased with increasing conductive layers from one to two, and then augmented with further increase in conductive layers. With respect to polymer type, the resistance and repeatability of the TPU based sensors was higher than the PDMS counterparts, whereas the sensitivity of the TPU based sensors was lower than the PDMS ones.
来源出处
Journal|[J]Polymer CompositesVolume 42, Issue 3. 2020. PP 1440-1450
DOI
https://doi.org/10.1002/PC.25914

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备注说明:

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