近场静电纺丝法制备Ag - NPs掺杂PVDF纳米复合纤维膜的压电性能表征。

ty10086 提交于 周三, 08/25/2021 - 16:00
文章英文标题
Characterization of Piezoelectric Properties of Ag-NPs Doped PVDF Nanocomposite Fibres Membrane Prepared by Near Field Electrospinning.
正文
本研究采用近场静电纺丝( NFES )技术,采用圆柱形集热器,通过制备的溶液制备大面积的永久性压电微纳米纤维。纳米银( Ag-NP ) /聚偏氟乙烯( PVDF )复合材料是一种性能优良的压电材料,可以制备出具有高灵敏度、高导电性的压电材料。本文采用基于近场静电纺丝( NFES )的可控静电纺丝技术,在纯PVDF纤维的基础上制备Ag-NP / PVDF复合静电纺丝纤维。将PVDF溶液浓度为18wt . %和6wt . %的硝酸银溶液直接写入旋转圆柱形集热器上,用于取向纤维PVDF / Ag-NP纤维,在柔性薄的聚对苯二甲酸乙二酯( PET )衬底上制备铜( Cu )叉指电极,以聚二甲基硅氧烷( PDMS )为封装,增强PVDF / Ag-NP器件的耐久性。PVDF / Ag-NP纤维的形貌及直径的测量采用纤维的扫描电镜( SEM )和光学显微照片( OM )。最后,结果表明PVDF / Ag-NP纤维直径可达~ 7μm。,在压电晶体β相结构中,通过X射线衍射( XRD )研究了2θ = 20.5˚处的高衍射峰。而在PVDF溶液中加入纳米银( Ag-NPs )后,其机电转换效率从~ 0.1 V提高到~ 1 V,可以说,证实和验证了在PVDF中加入Ag - NP可以提高PVDF的压电性能。
文章内容(英文)
In this study, Near-field electrospinning (NFES) technique used with a cylindrical collector to fabricate a large area permanent piezoelectric micro and nanofibers by a prepared solution. NFES requires a small electric field to fabricate fibers.;The objective of this paper to investigate silver nanoparticle (Ag-NP)/ Polyvinylidene fluoride (PVDF) composite as the best piezoelectric material with improved properties to produced tremendously flexible and sensitive piezoelectric material with pertinent conductance.;In this paper we used controllable electrospinning technique based on Near-field electrospinning (NFES)The process parameter for Ag-NP/PVDF composite electrospun fiber based on pure PVDF fiber. A PVDF solution concentration of 18 wt.% and 6 wt.% silver nitrate which is relative to the weight of PVDF wt.% with 1058 µS conductivity fibers have been directly written on a rotating cylindrical collector for aligned fiber PVDF/Ag-NP fibers are patterned on fabricated copper (Cu) interdigitated electrodes were implemented on a thin flexible polyethylene terephthalate (PET) substrate and Polydimethylsiloxane (PDMS) used as a package to enhance the durability of the PVDF/ Ag-NP device.;A notable effect on the piezoelectric response has been observed after Ag-NP addition confirmed by XRD characterization and tapping test of Ag-NP/PVDF composite fiber. The morphology of the PVDF/Ag-NP fibers and measure diameter by scanning electron microscopy (SEM) and Optical micrograph (OM), of fiber. Finally, The result shows that diameter of PVDF/Ag-NP fibers up to ~7 μm. The. High diffraction peak at 2θ = 20.5˚ was investigated by X-ray diffraction (XRD) in the piezoelectric crystal β-phase structure. While the electromechanical conversion is found enhance from ~0.1 V to ~1 V by the addition of silver nanoparticles (Ag-NPs) in the PVDF solution.;In conclusion, we can say that confirmed and validated the addition of Ag-NP in PVDF could enhance the piezoelectric property by using NFES technique with improved crystalline phase content can be useful for a wide range of power and sensing applications like biomedical devices and energy harvesting, among others.
来源出处
Journal|[J]Combinatorial Chemistry & High Throughput Screening2021.
DOI
https://doi.org/10.2174/1386207324666210302100728

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